کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5149169 | 1497879 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhanced performance of solid oxide fuel cells using BaZr0.2Ce0.7Y0.1O3âδ thin films
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Thin-film BaZr0.2Ce0.7Y0.1O3âδ (BZCY) is a promising electrolyte material for intermediate-temperature solid oxide fuel cells. However, a major drawback is its poor adhesion to porous electrodes. For achieving a high adhesion of thin BZCY films to anodes, a mixed electrolyte containing La0.80Sr0.20Ga0.80Mg0.20O3âδ (LSGM) and BZCY is deposited onto a porous NiO-BZCYYb anode, followed by the deposition of a 4 μm-thick BZCY electrolyte layer over the mixed electrolyte layer by e-beam vapor deposition. The formation of a fully dense and well-adhered BZCY layer is confirmed. The prepared cell exhibits excellent potential for achieving high power densities with various fuels. The maximum power densities of a single cell are 1.21, 0.93, and 0.76 W cmâ2 at 650 °C with hydrogen, methane, and biogas, respectively. Furthermore, the maximum power densities are 0.26, 0.12, and 0.21 W cmâ2 at 500 °C with hydrogen, methane, and biogas, respectively. The ionic conductivities of the electrolyte layer are 1.2 Ã 10â2 S cmâ1 and 3.1 Ã 10â3 S cmâ1 at 650 and 500 °C respectively, with an activation energy of 0.46 eV.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 353, 15 June 2017, Pages 254-259
Journal: Journal of Power Sources - Volume 353, 15 June 2017, Pages 254-259
نویسندگان
Dimpul Konwar, Bang Ju Park, Padmini Basumatary, Hyon Hee Yoon,