کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5149417 | 1497889 | 2017 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Temperature effects on cycling stability of Li plating/stripping on Ta-doped Li7La3Zr2O12
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
This paper reports on the cycling stability of Li plating/stripping on Li6.6La3Zr1.6Ta0.4O12 [LLZ(Ta0.4)] with high sintering density at 25, 60, and 100 °C. Plated/stripped Li thicknesses are sequentially increased to 200 nm, 1.0 μm, and 2.0 μm after every ten cycles. The overpotential gradually increases with cycling Li plating/stripping processes, and the cells eventually short-circuit at 25 and 60 °C. However, the cycling stability of Li plating/stripping significantly improves at 100 °C, and the short-circuiting is prevented perfectly. Moreover, the cycling stability of Li plating/stripping at 25 °C is dramatically improved by pre-cycling the cell at 100 °C. Only heating a cell with Li metal at 100 °C for the same duration does not improve the cycling stability of the cell. It is hence considered that forced migrations of Li atoms and ions across entire Li/LLZ(Ta0.4) interfaces at 100 °C change the properties of the interfacial regions even for the following plating/stripping cycles at 25 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 343, 1 March 2017, Pages 207-215
Journal: Journal of Power Sources - Volume 343, 1 March 2017, Pages 207-215
نویسندگان
Fumihiro Yonemoto, Atsuki Nishimura, Munekazu Motoyama, Nobuo Tsuchimine, Susumu Kobayashi, Yasutoshi Iriyama,