کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5149485 | 1497884 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Amorphous LiCoO2Li2SO4 active materials: Potential positive electrodes for bulk-type all-oxide solid-state lithium batteries with high energy density
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Newly amorphous Li2-x/100Cox/100S1-x/100O4-x/50 (xLiCoO2·(100-x)Li2SO4 (mol%)) positive electrode active materials are synthesized using mechanochemical techniques. SEM observation indicates that average radii of the Li1.2Co0.8S0.2O2.4 (80LiCoO2·20Li2SO4 (mol%)) particles are about 3 μm. HR-TEM images indicate that the particles comprise nano-crystalline and amorphous phases. The crystalline phase is attributable to cubic LiCoO2 phase. These active materials exhibit a high electronic conductivity of around 10â5-10â1 S cmâ1 and an ionic conductivity of around 10â7-10â6 S cmâ1 at room temperature. Bulk-type all-oxide solid-state cells (LiIn alloy/Li3BO3-based glass-ceramic electrolyte/amorphous Li2-x/100Cox/100S1-x/100O4-x/50) are fabricated by pressing at room temperature without high temperature sintering. Although the cell with the milled LiCoO2 shows no capacity, the cell using the Li1.2Co0.8S0.2O2.4 electrode with no conductive components (ca. 150 μm thickness) operates as a secondary battery at 100 °C, with an average discharge potential of 3.3 V (vs. Li+/Li) and discharge capacity of 163 mAh gâ1. A positive electrode with large amounts of active materials is suitable for achieving high energy density in all-solid-state batteries. These newly synthesized amorphous Li2-x/100Cox/100S1-x/100O4-x/50 electrodes with ionic and electronic conductivities and good processability meet that demand.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 348, 30 April 2017, Pages 1-8
Journal: Journal of Power Sources - Volume 348, 30 April 2017, Pages 1-8
نویسندگان
Kenji Nagao, Akitoshi Hayashi, Minako Deguchi, Hirofumi Tsukasaki, Shigeo Mori, Masahiro Tatsumisago,