کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5149858 | 1497892 | 2017 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effect of “bridge” on the performance of organic-inorganic crosslinked hybrid proton exchange membranes via KH550
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
A series of novel organic-inorganic crosslinked hybrid proton exchange membranes were prepared using sulfonated poly(arylene ether ketone sulfone) polymers containing carboxyl groups (C-SPAEKS), (3-aminopropyl)-triethoxysilane (KH550), and tetraethoxysilane (TEOS). KH550 acted as a “bridge” after reacting with carboxyl and sulfonic groups of C-SPAEKS to form covalent and ionic crosslinked structure between the C-SPAEKS and SiO2 phase. The crosslinked hybrid membranes (C-SPAEKS/K-SiO2) were characterized by FT-IR spectroscopy, TGA, and electrochemistry, etc. The thermal stability, mechanical properties and proton conductivity of the crosslinked hybrid membranes were improved by the presence of both crosslinked structure and inorganic phase. The proton conductivity of C-SPAEKS/K-SiO2-8 was recorded as 0.110 S cmâ1, higher than that of Nafion® (0.028 S cmâ1) at 120 °C. Moreover, the methanol permeability of the C-SPAEKS/K-SiO2-8 was measured as 3.86 Ã 10â7 cm2 sâ1, much lower than that of Nafion® 117 membranes (29.4 Ã 10â7 cm2 sâ1) at 25 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 340, 1 February 2017, Pages 126-138
Journal: Journal of Power Sources - Volume 340, 1 February 2017, Pages 126-138
نویسندگان
Hailan Han, Hai Qiang Li, Meiyu Liu, Lishuang Xu, Jingmei Xu, Shuang Wang, Hongzhe Ni, Zhe Wang,