کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5149885 | 1497894 | 2017 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Influence of the structure of the anion in an ionic liquid electrolyte on the electrochemical performance of a silicon negative electrode for a lithium-ion battery
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
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چکیده انگلیسی
We investigated the influence of the anions in ionic liquid electrolytes on the electrochemical performance of a silicon (Si) negative electrode for a lithium-ion battery. While the electrode exhibited poor cycle stability in tetrafluoroborate-based and propylene carbonate-based electrolytes, better cycle performance was achieved in bis(fluorosulfonyl)amide (FSA-)- and bis(trifluoromethanesulfonyl)amide (TFSA-)-based electrolytes, in which the discharge capacity of a Si electrode was more than 1000Â mAÂ h gâ1 at the 100th cycle. It is considered that a surface film derived from FSA-- and TFSA--based electrolytes effectively suppressed continuous decomposition of the electrolyte. In a capacity limitation test, a discharge capacity of 1000Â mAÂ h gâ1 was maintained even after about the 1600th cycle in the FSA--based electrolyte, which corresponds to a cycle life almost twice as long as that in TFSA--based electrolyte. This result should be explained by the high structural stability of FSA--derived surface film. In addition, better rate capability with a discharge capacity of 700Â mAÂ h gâ1 was obtained at a high current rate of 6Â C (21Â AÂ gâ1) in FSA--based electrolyte, which was 7-fold higher than that in TFSA--based electrolyte. These results clarified that FSA--based ionic liquid electrolyte is the most promising candidate for Si-based negative electrodes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 338, 15 January 2017, Pages 103-107
Journal: Journal of Power Sources - Volume 338, 15 January 2017, Pages 103-107
نویسندگان
Kazuki Yamaguchi, Yasuhiro Domi, Hiroyuki Usui, Masahiro Shimizu, Kuninobu Matsumoto, Toshiki Nokami, Toshiyuki Itoh, Hiroki Sakaguchi,