کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5150245 | 1497902 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
All-solid-state lithium-sulfur batteries with three-dimensional mesoporous electrode structures
ترجمه فارسی عنوان
باتری های لیتیوم سولفور با حالت جامد دولتی با ساختارهای الکترود مزوپور سه بعدی
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کلمات کلیدی
باتری همه حالت جامد، لیتیم باطری گوگرد، ماتریکس کربن، کربن مرجانی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
Although the characteristics of lithium-sulfur batteries are advantageous for various applications, batteries with liquid electrolytes show capacity fading due to the dissolution of polysulfides. All-solid-state lithium-sulfur batteries with highly reversible characteristics are developed using a three-dimensional carbon matrix framework structure for the sulfur cathode. Sulfur is introduced into a carbon replica framework with a pore size of 8-100Â nm. The composite electrode structure provides high electronic conduction and allows high cathode utilization during the battery reaction. The capacity of cells using a LiAl alloy as the negative electrode and the thio-LISICON (lithium superionic conductor) electrolyte increases when the pore size of the carbon replica is decreased from 100Â nm to less than 15Â nm. The highest capacity is obtained for the carbon replica with a pore size of 8.6Â nm and a wall thickness of 4.7Â nm. An examination of the relationship between the charge-discharge capacity and the structure of carbon replicas with different pore sizes and wall thicknesses indicates that three-dimensional highly ordered mesoporous carbon with a small pore size is a promising electrode structure for lithium-sulfur all-solid-state batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 330, 31 October 2016, Pages 120-126
Journal: Journal of Power Sources - Volume 330, 31 October 2016, Pages 120-126
نویسندگان
Miki Nagao, Kota Suzuki, Yuki Imade, Mitsuru Tateishi, Ryota Watanabe, Toshiyuki Yokoi, Masaaki Hirayama, Takashi Tatsumi, Ryoji Kanno,