کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5150316 | 1498233 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electronic conduction mechanism and defect chemical model of LaNi0.4Fe0.6O3 â δ
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Electronic conduction mechanism and defect chemical model of LaNi0.4Fe0.6O3 â δ Electronic conduction mechanism and defect chemical model of LaNi0.4Fe0.6O3 â δ](/preview/png/5150316.png)
چکیده انگلیسی
In order to elucidate the electronic conduction mechanism and defect chemical model of LaNi0.4Fe0.6O3 â δ at high temperatures, electrical conductivity (Ï), Seebeck coefficient (S), and oxygen vacancy concentration (δ) of LaNi0.4Fe0.6O3 â δ were measured as a function of oxygen partial pressure (p(O2)) and temperature. Relatively large Ï and small positive S values are observed, which indicates the contribution of ionic conduction is negligibly small to thermoelectric power and the major electronic carrier is a hole. From the analysis of Ï and S, it is expected that the LaNi0.4Fe0.6O3 â δ has small polaron hopping conduction mechanism where an electron is localized on the Fe. The slope of δ vs p(O2) shows a minimum value near the stoichiometric composition and the δ increases as p(O2) reduces and temperature increases. The relationship between δ vs. log p(O2) is analyzed by a localized electron model and the behavior of the oxygen nonstoichiometry of LaNi0.4Fe0.6O3 â δ can be explained.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 310, 1 November 2017, Pages 148-153
Journal: Solid State Ionics - Volume 310, 1 November 2017, Pages 148-153
نویسندگان
R.A. Budiman, H.J. Hong, S. Hashimoto, T. Nakamura, K. Yamaji, K. Yashiro, K. Amezawa, T. Kawada,