کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5150399 | 1498235 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhanced ionic conductivity in phase stabilized yttria-doped zirconia nanowires
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Yttria-doped zirconia (YSZ) is a remarkable functional material with wide applications, including solid oxide fuel cells (SOFCs) and oxygen sensors, due to its excellent mechanical and electrical properties. However, the elevated operating temperatures using the conventional YSZ electrolytes for the solid ionic devices yield high cost and limited lifetime. Here we report YSZ nanowires with doping content rang of 0-10 mol% prepared by electrospinning. The variety of tetragonal and cubic phases in the nanowires has been detected, which demonstrates that in comparison to bulk counterparts, the high-temperature phases in zirconia-based nanowires could be stabilized at lower doping levels, owing to the critical crystallite size effect. The electrical conductivity of uniaxially aligned nanowires with respect to yttria content has been investigated. The highest ionic conductivity of 0.01 Scmâ 1 is achieved at a low temperature of 375 °C for the YSZ nanowires with 6.5 mol% yttria, which is 290 times enhancement over corresponding bulk.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 308, 1 October 2017, Pages 34-39
Journal: Solid State Ionics - Volume 308, 1 October 2017, Pages 34-39
نویسندگان
Wei Liu, Gang Ou, Lei Yao, Hiroki Nishijima, Wei Pan,