کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5150474 | 1498243 | 2017 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Redox activity of argyrodite Li6PS5Cl electrolyte in all-solid-state Li-ion battery: An XPS study
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Argyrodite Li6PS5Cl is a good candidate as solid electrolyte for bulk all-solid-state Li-ion batteries due to its high ionic conductivity and its good processability, although it shows some interface reactivity towards electrode active materials. In this work we have cycled LiCoO2/Li6PS5Cl/Li4Ti5O12 full cells and analyzed the interfacial mechanisms by surface-sensitive characterization techniques: Auger Electron Spectroscopy (AES) and X-ray Photoelectron Spectroscopy (XPS). We show that Li6PS5Cl has an electrochemical redox activity in the positive electrode. It is partially oxidized into LiCl, P2S5 and polysulfides Li2Sn upon charge, with some reversibility upon discharge. Li6PS5Cl also reacts with LiCoO2 upon cycling, leading to the formation of phosphates at the interface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Ionics - Volume 300, February 2017, Pages 78-85
Journal: Solid State Ionics - Volume 300, February 2017, Pages 78-85
نویسندگان
Jérémie Auvergniot, Alice Cassel, Dominique Foix, Virgine Viallet, Vincent Seznec, Rémi Dedryvère,