کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51546 | 46846 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Insights into the nature of alumina-supported MnOOH and its catalytic performance in the aerobic oxidation of benzyl alcohol
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
We report the synthesis of alumina-supported manganese catalysts by a homogeneous deposition–precipitation method and their catalytic application in the aerobic oxidation of benzyl alcohol. Benzyl alcohol conversion of 93% was achieved with benzaldehyde as the main product. This Mn-based catalyst can be recycled up to six times without losing catalytic activity. X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) indicated that MnOOH species are highly dispersed on the alumina surface at low Mn loadings (<10 wt.%). These MnOOH species aggregated into Mn3O4 crystallites at high Mn loadings.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 7, 10 March 2009, Pages 1122–1126
Journal: Catalysis Communications - Volume 10, Issue 7, 10 March 2009, Pages 1122–1126
نویسندگان
Qinghu Tang, Xiaonan Gong, Chengming Wu, Yuanting Chen, Armando Borgna, Yanhui Yang,