کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51619 | 46848 | 2008 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nitration of aromatic compounds with NO2/air catalyzed by sulfonic acid-functionalized ionic liquids
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
Nitration of aromatic compounds with NO2/air catalyzed by sulfonic acid-functionalized ionic liquid under solvent-free conditions is reported. A variety of ionic liquids [BSPy][HSO4], [BSPy][TfO], and [BSPy][pTSA] ([BSPy] = N-(4-hydroxsulfonylbutyl) pyridinium) were prepared. Their acidities were further investigated by Hammett method and the acidity-catalytic relationship was discussed. It was found that satisfactory results were obtained with [BSPy][HSO4]. Ionic liquids could be conveniently separated with the products and reused for five times with excellent yield of mono-nitration products and para-selectivity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 2, 15 November 2008, Pages 201–204
Journal: Catalysis Communications - Volume 10, Issue 2, 15 November 2008, Pages 201–204
نویسندگان
Guangbin Cheng, Xuelei Duan, Xiufang Qi, Chunxu Lu,