کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
51619 46848 2008 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nitration of aromatic compounds with NO2/air catalyzed by sulfonic acid-functionalized ionic liquids
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Nitration of aromatic compounds with NO2/air catalyzed by sulfonic acid-functionalized ionic liquids
چکیده انگلیسی

Nitration of aromatic compounds with NO2/air catalyzed by sulfonic acid-functionalized ionic liquid under solvent-free conditions is reported. A variety of ionic liquids [BSPy][HSO4], [BSPy][TfO], and [BSPy][pTSA] ([BSPy] = N-(4-hydroxsulfonylbutyl) pyridinium) were prepared. Their acidities were further investigated by Hammett method and the acidity-catalytic relationship was discussed. It was found that satisfactory results were obtained with [BSPy][HSO4]. Ionic liquids could be conveniently separated with the products and reused for five times with excellent yield of mono-nitration products and para-selectivity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 2, 15 November 2008, Pages 201–204
نویسندگان
, , , ,