کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51632 | 46848 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Liquid-phase dehydration of 1-phenylethanol over mordenite-like zeolites: Influence of Si/Al ratio
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Liquid-phase dehydration of 1-phenylethanol over mordenite-like zeolites: Influence of Si/Al ratio Liquid-phase dehydration of 1-phenylethanol over mordenite-like zeolites: Influence of Si/Al ratio](/preview/png/51632.png)
چکیده انگلیسی
The liquid-phase dehydration of 1-phenylethanol over mordenite-like zeolites, with different Si/Al ratios, was studied at 363 K using cyclohexane as solvent. It was determined that catalyst activity and selectivity greatly depended on the Si/Al ratio. The non-dealuminated mordenite showed the lowest activity, dehydrating 1-phenylethanol mainly to α-methylbenzyl ether via an intermolecular mechanism. Instead, intramolecular dehydration of 1-phenylethanol into styrene was mainly observed over dealuminated samples. Changes in catalytic performance with Si/Al ratio was explained on the basis of: (1) acid site density; (2) relative amount of strong acid sites respect to weak ones; (3) accessibility to strong acid sites.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 10, Issue 2, 15 November 2008, Pages 261–265
Journal: Catalysis Communications - Volume 10, Issue 2, 15 November 2008, Pages 261–265
نویسندگان
Nicolás M. Bertero, Carlos R. Apesteguía, Alberto J. Marchi,