کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51724 | 46851 | 2011 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Base-free copper-catalyzed aerobic oxidation of benzylic alcohols with N-benzylidene-N,N-dimethylthane-1,2-diamine and TEMPO
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Base-free copper-catalyzed aerobic oxidation of benzylic alcohols with N-benzylidene-N,N-dimethylthane-1,2-diamine and TEMPO Base-free copper-catalyzed aerobic oxidation of benzylic alcohols with N-benzylidene-N,N-dimethylthane-1,2-diamine and TEMPO](/preview/png/51724.png)
چکیده انگلیسی
Selective oxidation of alcohols using N-benzylidene-N,N-dimethylthane-1,2-diamine, CuBr2 and TEMPO as the catalytic system was developed. Catalyzed by this simple catalytic system in the absence of any external base, various benzylic alcohols could be oxidized to their corresponding aldehydes with excellent yields in CH3CN/H2O (v/v = 1/1) under 0.2 MPa O2 at 80 °C.
Figure optionsDownload as PowerPoint slideHighlights
► N-benzylidene-N,N-dimethylthane-1,2-diamine, CuBr2 and TEMPO as a catalyst system.
► The simple ligand could be easily synthesized.
► Efficient aerobic oxidation of benzylic alcohols into aldehydes under mild conditions.
► the oxidations occurred well without any external base, being unlike the previous Cu/TEMPO systems.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 14, Issue 1, 25 October 2011, Pages 92–95
Journal: Catalysis Communications - Volume 14, Issue 1, 25 October 2011, Pages 92–95
نویسندگان
Qiufen Wang, Ying Zhang, Gengxiu Zheng, Zhongzhen Tian, Guanyu Yang,