کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
51867 | 46857 | 2008 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidation of alkanes with hydrogen peroxide catalyzed by Schiff base complexes covalently anchored to polyoxometalate
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
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چکیده انگلیسی
The catalytic activity of a hybrid compound [Fe(salen)-POM] (1) consisting of metallosalen moiety, [FeIII(salen)Cl], covalently linked to a Keggin type polyoxometalate, K8SiW11O39 (POM), in the oxidation of hydrocarbons with hydrogen peroxide was investigated. Reaction products were identified by gas chromatography and satisfactory yields were obtained. While, the Fe(salen)-POM catalyst showed high catalytic activity and product selectivity in the oxidation reactions, the metallosalen alone, [FeIII(salen)Cl], showed very poor catalytic activity in these reactions. The ability of various transition metal ions in this oxidation system was also investigated. Among a series of hybrid compounds, Fe(salen)-POM showed the highest activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 9, Issue 13, 20 July 2008, Pages 2171–2174
Journal: Catalysis Communications - Volume 9, Issue 13, 20 July 2008, Pages 2171–2174
نویسندگان
Valiollah Mirkhani, Majid Moghadam, Shahram Tangestaninejad, Iraj Mohammadpoor-Baltork, Nahid Rasouli,