کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52271 | 46867 | 2008 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization of Zr6Nb2O17 synthesized by a peroxo route as a novel solid acid
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The impregnation of hydrated zirconia at pH ∼0.5 with a solution of peroxoniobium(V) complex, [Nb2(O2)3]4+, ensuring a ZrO2:Nb2O5 mole ratio of 6:1 followed by calcination at 873 K resulted in the formation of a Zr6Nb2O17 solid solution. The structure of this compound was confirmed by XRD. The surface acidity was investigated by in situ FT-IR spectroscopy using 2,6-dimethylpyridine (lutidine). Zr6Nb2O17 has a sufficient amount of Brønsted acid sites necessary for the stabilization of dispersed Pd(II) species. The potential of the Pd-promoted Zr6Nb2O17 as a catalyst for the reduction of NO with methane was evaluated by studying the reactivity of adsorbed NOx species toward the hydrocarbon.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 9, Issue 5, 20 March 2008, Pages 874–879
Journal: Catalysis Communications - Volume 9, Issue 5, 20 March 2008, Pages 874–879
نویسندگان
Margarita Kantcheva, Hülya Budunoğlu, Olga Samarskaya,