کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52338 | 46870 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Investigation of catalytic activity of cobalt–Schiff base complex covalently linked to the polyoxometalate in the alkene and benzyl halide oxidation with hydrogen peroxide
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Investigation of catalytic activity of cobalt–Schiff base complex covalently linked to the polyoxometalate in the alkene and benzyl halide oxidation with hydrogen peroxide Investigation of catalytic activity of cobalt–Schiff base complex covalently linked to the polyoxometalate in the alkene and benzyl halide oxidation with hydrogen peroxide](/preview/png/52338.png)
چکیده انگلیسی
The catalytic activity of a hybrid compound Co(salen)–POM (1) consisting of cobalt(salen) [salen = N,N′-bis(salicylidene)ethylenediamine] complex covalently linked to a Keggin type polyoxometalate (POM) was studied, for the first time, in the oxidation of various olefins in acetonitrile, using hydrogen peroxide as an oxygen source. The complex (1) can catalyze oxidation of various olefins including non-activated terminal olefins. The effect of other parameters such as solvent, oxidant and temperature were also investigated. The selective oxidation of benzyl halides to their corresponding carbonyl compounds by complex (1), as catalyst, was also examined at room temperature.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 9, Issue 2, February 2008, Pages 219–223
Journal: Catalysis Communications - Volume 9, Issue 2, February 2008, Pages 219–223
نویسندگان
Valiollah Mirkhani, Majid Moghadam, Shahram Tangestaninejad, Iraj Mohammadpoor-Baltork, Nahid Rasouli,