کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52477 | 46875 | 2007 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: On the structure-sensitivity of 2-butanol dehydrogenation over Cu/SiO2 cogelled xerogel catalysts On the structure-sensitivity of 2-butanol dehydrogenation over Cu/SiO2 cogelled xerogel catalysts](/preview/png/52477.png)
Cu/SiO2 cogelled xerogel catalysts were synthesized by cogelation of tetraethoxysilane (TEOS) and chelates of Cu with 3-(2-aminoethylamino)-propyltrimethoxysilane (EDAS). The resulting catalysts are composed of metallic crystallites with a diameter of about 3 nm located inside microporous silica particles and larger metallic particles with a diameter of 8–30 nm located outside silica network. Cu/SiO2 catalysts were tested for 2-butanol dehydrogenation. This reaction over Cu/SiO2 cogelled xerogel catalysts is a structure-sensitive reaction: large metallic particles located outside silica particles are responsible for the dehydrogenation reaction, while small metallic particles located inside silica particles do not participate to the reaction.
Journal: Catalysis Communications - Volume 8, Issue 12, December 2007, Pages 2032–2036