کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
52683 46880 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Catalytic oxidation of isophorone to ketoisophorone over ruthenium supported MgAl-hydrotalcite
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Catalytic oxidation of isophorone to ketoisophorone over ruthenium supported MgAl-hydrotalcite
چکیده انگلیسی

Selective oxidation of α-isophorone to ketoisophorone was carried out over Ruthenium supported MgAl-hydrotalcite in the temperature range 40–100 °C using acetonitrile as a solvent and tert-butyl hydroperoxide as an oxidant. The influence of various reaction parameters, such as reaction temperature, reaction time, substrate: catalyst mass ratio, substrate:oxidant mole ratio, and nature of solvent was studied. A maximum conversion of 60% KIP with 100% selectivity in 48 h was observed with a substrate: catalyst mass ratio of 10:1 at 60 °C.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 8, Issue 7, July 2007, Pages 1156–1160
نویسندگان
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