کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
52797 | 46887 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidation of cyclohexane promoted by [Fe(III)(Salen)Cl] and [Mn(III)(Salen)Cl]
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Salen complexes of iron(III) and manganese(III) were synthesized and employed as catalysts in the oxidation of cyclohexane, using hydrogen peroxide and tert–butylhydroperoxide. The reactions were carried out in acetonitrile at room temperature. The catalysts were characterized by infrared and Mössbauer spectroscopy, elemental analysis, conductivity and cyclic voltammetry. Conversions up to 10.2% (4.2% and 6.0% yields for cyclohexanol and cyclohexanone, respectively) were obtained for the system [Fe(III)(Salen)Cl]/tBuOOH.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Communications - Volume 8, Issue 1, January 2007, Pages 69–72
Journal: Catalysis Communications - Volume 8, Issue 1, January 2007, Pages 69–72
نویسندگان
Gisele C. Salomão, Mara H.N. Olsen, Valderes Drago, Christiane Fernandes, L. Cardozo Filho, O.A.C. Antunes,