کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5351542 | 1503671 | 2014 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Enhancement photocatalytic degradation of rhodamine B on nanoPt intercalated Zn-Ti layered double hydroxides
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
NanoPt intercalated Zn-Ti layered double hydroxides (LDHs) have been synthesized by ionic exchange and photochemical reduction method from Zn-Ti LDHs in H2PtCl6 solution. X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), N2 adsorption at 77Â K, UV-vis analysis and the electrochemical impedance were adopted to investigate the structure, surface, micromorphology, photoresponsive and electrochemical properties of the as-synthesized samples. The combination of Zn-Ti-LDHs and Pt introduces some properties of Pt into photocatalysis such as excellent conductivity and controllability. Remarkable 17-fold enhancement in the degradation of rhodamine B (RhB) reaction was observed on as-prepared Pt/Zn-Ti LDHs compared with pure Zn-Ti LDHs under simulated sunlight irradiation. The enhanced photocatalytic activity could be attributed to high specific surface (111.46Â m2/g), extended photoresponding range, the negative shift in the flat-band potentials and the high migration efficiency of photoinduced electrons, which may suppress the charge recombination effectively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 293, 28 February 2014, Pages 345-351
Journal: Applied Surface Science - Volume 293, 28 February 2014, Pages 345-351
نویسندگان
Guixiang Chen, Shengming Qian, Xinman Tu, Xiaoyong Wei, Jianping Zou, Lehui Leng, Shenglian Luo,