Adsorption and photodegradation of methylene blue by iron oxide impregnated on granular activated carbons in an oxalate solution

The photocatalytic adsorbents BAU-OA, BAU-CL and BAU-HA with varying iron oxide content (9-10 mass%) were prepared by heat treatment at 250 °C from commercial activated carbon (BAU) impregnated with iron oxalate, chloride, tris-benzohydroxamate, respectively. The XRD patterns showed amorphous structure in the BAU-CL sample (SBET 50 m2/g) and low crystallinity (as FeOOH and Fe2O3 phases) in the BAU-HA and BAU-OA samples (SBET 4 and 111 m2/g, respectively). The methylene blue adsorption capacities was decreased in order of BAU-OA < BAU-CL < BAU-HA sample and the adsorption followed Langmuir model. The apparent MB photodegradation rate constant (kapp) was increased in same order BAU-HA < BAU-CL < BAU-OA under the standard experimental conditions (initial MB concentrations 0.015-0.025 mM; sample content - 10 mg/l; initial oxalic acid concentration - 0.43 mM; pH 3-4; UV illumination). The process included high efficiency combination of adsorption, heterogeneous and homogeneous catalysis under UV and solar lights illumination without addition of hydrogen peroxide. The detoxification of water sample containing organic dyes was confirmed after combined sorption-photocatalytic treatment.