کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5358312 | 1503617 | 2015 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
On structure and methylene blue degradation activity of an Aurivillius-type photocatalyst of Bi4V2O11 nanoparticles
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Aurivillius-type photocatalyst of Bi4V2O11 nanoparticles with an average particle size of 45Â nm was prepared by the modified Pechini method. The sample was investigated by X-ray powder diffraction (XRD) and the structural refinement. The nanoparticles were characterized by scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopic (XPS) and UV-vis absorption spectrum. Bi4V2O11 nanoparticles show an efficient absorption in the UV-vis light wavelength region with a narrowed band gap energy of 2.08Â eV and an indirect allowed electronic transition. The photocatalytic activities of Bi4V2O11 nanoparticles were evaluated by photodegradation of methylene blue (MB) under visible-light irradiation in air atmosphere. These results indicate that Bi4V2O11 could be a potential photocatalyst driven by visible-light. Hybridization of the 6s and 6p orbitals of Bi3+ and the resulting lone electron pair yields interesting properties. The effective photocatalytic activity was discussed on the base of the crystal structure characteristic such as polar (VO3.5â¡0.5)2â anionic groups, Aurivillius-type (Bi2O2)2+ layers and long distance of the nearest V-V in the lattices, etc.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 347, 30 August 2015, Pages 719-726
Journal: Applied Surface Science - Volume 347, 30 August 2015, Pages 719-726
نویسندگان
Yuting Lu, Yinfu Pu, Jing Wang, Chuangxiang Qin, Cuili Chen, Hyo Jin Seo,