کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5359354 | 1503677 | 2013 | 22 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Increased charge transfer of PVDF-HFP based electrolyte by addition of graphite nanofiber and its application in dye-sensitized solar cells
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The PEO and PVDF-HFP mixtures were used as polymer electrolytes in solid-state dye-sensitized solar cells (DSSCs). Correlation between the ionic conductivity and cell performance by varying the composition of polymer electrolytes was investigated to elucidate the importance of the ionic conductivity in determining the charge transfer and energy conversion efficiency of solid-state DSSCs. In this work, for increasing the ionic conductivity and charge transfer, GNF was added to the polymer electrolyte. The ionic conductivity of polymer electrolyte containing GNF (0.005Â g) is 8.67Â ÃÂ 10â4Â SÂ cmâ1 and pristine polymer electrolyte is 3.81Â ÃÂ 10â4Â SÂ cmâ1. The charge transfer of GNF (0.005Â g) added DSSCs is faster than the other samples, the electron transport time is 1.53Â ms and electron life time is 27.20Â ms. The increase of current density with the polymer electrolyte containing GNF (0.005Â g) can be possibly attributed to the direct contact between dye/TiO2 and Iâ/I3â that will improve the charge transportation. The highest energy conversion efficiency of 4.60% is obtained for polymer electrolyte containing GNF (0.005Â g).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 287, 15 December 2013, Pages 8-12
Journal: Applied Surface Science - Volume 287, 15 December 2013, Pages 8-12
نویسندگان
Xing Guan Zhao, En Mei Jin, Hal-Bon Gu,