کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5359503 1388248 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Removal of nickel(II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Removal of nickel(II) ions from aqueous solutions using the natural clinoptilolite and preparation of nano-NiO on the exhausted clinoptilolite
چکیده انگلیسی
The natural zeolite tuff (clinoptilolite) from a Serbian deposit has been studied as adsorbent for Ni(II) ions from aqueous solutions. Its sorption capacity at 298 K varies from 1.9 mg Ni g−1 (for the initial solution concentration of 100 mg Ni dm−3) to 3.8 mg Ni g−1 (for C0 = 600 mg Ni dm−3) and it increases 3 times at 338 K. The sorption is best described by the Sips isotherm model. The sorption kinetics follows the pseudo-second-order model, the activation energies being 7.44, 5.86, 6.62 and 6.63 kJ mol−1 for C0 = 100, 200, 300 and 400 mg Ni dm−3, respectively. The sorption involves a film diffusion, an intra-particle diffusion, and a chemical cation-exchange between the Na+ ions of clinoptilolite and the Ni2+ ions. The sorption is endothermic (ΔH° being 37.9, 33.4, 30.0, 27.7 and 24.3 kJ mol−1 for C0 = 100, 200, 300, 400 and 600 mg Ni dm−3, respectively) and spontaneous in the 298-338 K temperature range. Thermal treatment of the Ni(II)-loaded clinoptilolite results in the formation of spherical nano-NiO particles of approx. 5 nm in diameter which are randomly dispersed in the clinoptilolite lattice.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 257, Issue 5, 15 December 2010, Pages 1524-1532
نویسندگان
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