کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5362021 | 1388280 | 2009 | 6 صفحه PDF | دانلود رایگان |

A novel electrode having the compositional sequence Si/TiOx/Pt/TiOx was developed for ozone electrogeneration. The spin-coating method, the sputtering deposition technique, and a post-annealing procedure were all combined to assemble the electrode composition. A two-compartment electrolytic cell separated by a Nafion membrane was used to generate ozone galvanostatically. The X-ray photon electron spectroscopy (XPS) and atomic force microscopy (AFM) were used to reveal the electrode composition and morphology. The influence of several factors including the electrode's annealing temperature, the electrolyte composition, and the electrolysis' current density on the efficiency of ozone production was investigated. A maximum ozone generation efficiency of 2.5% was obtained at 74Â mAÂ cmâ2 at room temperature. Interestingly, the electrode preserved (ca. 80%) of its original activity to produce ozone after 50Â h of continues electrolysis at 74Â mAÂ cmâ2 at room temperature.
Journal: Applied Surface Science - Volume 255, Issue 20, 30 July 2009, Pages 8458-8463