Surface acid etching of (BiO)2CO3 to construct (BiO)2CO3/BiOX (X = Cl, Br, I) heterostructure for methyl orange removal under visible light

A series of (BiO)2CO3/BiOX (X = Cl, Br, I) heterostructured photocatalysts were synthesized through acid etching method and characterized by XRD, DRS, SEM and HRTEM, respectively. Under visible light (λ > 400 nm), (BiO)2CO3/BiOX displayed much higher photocatalytic activity than pure (BiO)2CO3 and corresponding BiOX for the degradation of methyl orange (MO). The photocatalytic activities of the as-prepared samples increased following this order: (BiO)2CO3/BiOCl < (BiO)2CO3/BiOBr < (BiO)2CO3/BiOI. The enhanced photocatalytic activities could be attributed to the function of heterojunction interface between (BiO)2CO3 and BiOX. Moreover, except for the role of heterostructure, the excellent photocatalytic performance of (BiO)2CO3/BiOI also originated from its good visible light absorption.

Novel (BiO)2CO3/BiOX (X = Cl, Br, I) heterostructured photocatalysts synthesized through one-step acid etching method displayed the enhanced photocatalytic activity than pure (BiO)2CO3 and the corresponding BiOX (X = Cl, Br, I) for the degradation of MO under visible light (l>400 nm). Comparatively, (BiO)2CO3/BiOI revealed the best photocatalytic activity among (BiO)2CO3/BiOCl, (BiO)2CO3/BiOBr and (BiO)2CO3/BiOI, which is largely attributed to the excellent separation of photocarriers through the p-n junction and its good visible light absorption.Highlights► (BiO)2CO3/BiOX (X = Cl, Br, I) were synthesized through acid etching method. ► (BiO)2CO3/BiOX displayed higher activity than single (BiO)2CO3 and BiOX. ► (BiO)2CO3 and BiOX constructed efficient p-n junction (BiO)2CO3/BiOX. ► (BiO)2CO3/BiOX p-n junction facilitated the separation of electrons and holes.