کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5368624 1388404 2010 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Effect of Fe state on electrocatalytic activity of Pd-Fe/C catalyst for oxygen reduction
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Effect of Fe state on electrocatalytic activity of Pd-Fe/C catalyst for oxygen reduction
چکیده انگلیسی

The carbon-supported Pd-Fe catalyst (Pd-Fe/C) is prepared in the H2O/tetrahydrofuran (THF) mixture solvent under the low temperature. The homemade Pd-Fe/C catalyst contains two forms of iron species, alloying and non-alloying Fe. The alloying Fe species is hardly dissolved in 0.5 M H2SO4 solution, while the non-alloying Fe species is easily dissolved in 0.5 M H2SO4 solution. The electrochemical measurements show the electrocatalytic activity of the Pd-Fe/C catalyst with the acid treatment for the oxygen reduction is higher than that of the Pd-Fe/C catalyst without the acid treatment, illustrating that the non-alloying Fe species suppresses the electrocatalytic activity of the Pd-Fe/C catalyst. In contrast, the alloying Fe species promotes the electrocatalytic activity of the Pd-Fe/C catalyst for the oxygen reduction, which is likely attributed to the change of the electron structure of Pd atom and/or bond length of Pd-Pd in the Pd-Fe/C catalyst.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 256, Issue 13, 15 April 2010, Pages 4196-4200
نویسندگان
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