کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5369935 1388465 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Observation of metastable erbium trihydride
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Observation of metastable erbium trihydride
چکیده انگلیسی

The γ phase of the erbium-hydrogen system is a hexagonal trihydride that is not predicted to be stable at room temperature without an overpressure of hydrogen gas. Herein, we report the creation of both, a thin film and powder of erbium trihydride that is metastable at ambient conditions. The presence of the hexagonal γ phase was determined by X-ray diffraction (XRD). The ratio of the total moles of hydrogen isotopes (hydrogen and deuterium) to moles of erbium, (H + D):Er, have been confirmed by elastic recoil detection (ERD)/Rutherford backscattering spectroscopy (RBS). Auger electron spectroscopy (AES) depth profiles and X-ray photoelectron spectroscopy (XPS) revealed the presence of an oxide layer that may account for the metastable behavior of the thin film.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Surface Science - Volume 253, Issue 5, 30 December 2006, Pages 2597-2602
نویسندگان
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