کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5375284 | 1504291 | 2010 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Threshold photoelectron studies of isoxazole over the energy range 9.9-30Â eV
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The threshold photoelectron spectrum of the isoxazole molecule, C3H3NO has been measured over the photon energy range 9.9-30 eV with the use of synchrotron radiation. In the 9.9-10.8 eV range, corresponding to photoionization from the highest occupied molecular orbital 3aâ³(Ï3), seven well resolved vibrational series have been observed and their modes are tentatively assigned. A strong adiabatic ionization, with an energy of 11.132 ± 0.003 eV corresponding to the 2aâ³(Ï2) band, has also been observed. This is followed by a single vibrational series of the νC-H stretching mode. Photoelectron bands in the energy region 13-30 eV have also been identified, some for the first time.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 367, Issues 2â3, 8 February 2010, Pages 75-79
Journal: Chemical Physics - Volume 367, Issues 2â3, 8 February 2010, Pages 75-79
نویسندگان
Marcin Dampc, Brygida Mielewska, Michele R.F. Siggel-King, George C. King, Bhalamurugan Sivaraman, Sylwia PtasiÅska, Nigel Mason, Mariusz Zubek,