کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5376580 1504327 2007 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Density dependence of optical Kerr lens signals in neat N2O and CO2
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Density dependence of optical Kerr lens signals in neat N2O and CO2
چکیده انگلیسی
Optical Kerr lens spectroscopy has been employed to study the reorientation dynamics of N2O and CO2 at the reduced densities 0.8-2.0 and different temperatures in a newly constructed high pressure cell. The transient birefringence induced in the medium by an ultrashort (1 1 0 fs) non-resonant pump beam at 400 nm was monitored by a second, time-delayed non-resonant probe beam at 800 nm. The transient change of the probe beam diameter was detected in the far field using a small-area photodiode. Measurements employing parallel and perpendicular polarization allowed us to extract the nuclear and electronic components of the Kerr effect, where the latter one was by far weaker for both CO2 and N2O. Accurate time constants for the reorientation dynamics of the CO2 and N2O molecules were extracted from the tail of the nuclear Kerr response. In the case of CO2 the time constants τreorientation were between 210 and 280 fs and in good agreement with previous data from NMR and OHD-OKE experiments as well as MD simulations. Reorientation time constants for N2O were in the range between 200 and 340 fs, and thus very similar to CO2. In the density range studied, τreorientation increases with increasing viscosity and decreasing temperature, in agreement with Stokes-Einstein-Debye diffusive models.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics - Volume 331, Issues 2–3, 8 January 2007, Pages 403-409
نویسندگان
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