کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
54048 46994 2015 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Sulfonic acid functionalized mesoporous ZSM-5: Synthesis, characterization and catalytic activity in acidic catalysis
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Sulfonic acid functionalized mesoporous ZSM-5: Synthesis, characterization and catalytic activity in acidic catalysis
چکیده انگلیسی


• SO3H-Meso ZSM-5 catalyst showed improved acidity and mesoporosity.
• SO3H-Meso ZSM-5 exhibited enhanced catalytic activity than Meso ZSM-5 and SO3H-ZSM-5.
• Higher loading of sulfonic acid functional groups led to higher yield of products.

Sulfonic acid functionalized mesoporous ZSM-5 (SO3H-Meso ZSM-5) were prepared by post-grafting of 3-mercaptopropyltriethoxysilane with various loading in the range of 10–50 wt% followed by oxidation of thiol using H2O2 to generate the corresponding sulfonic acid group. Grafting of organic moieties was evidenced by elemental analysis, 29Si & 13C-NMR and X-ray photoelectron spectroscopy. The SO3H-Meso ZSM-5 catalyst with improved acidity and mesoporosity exhibited enhanced catalytic activity in acid-catalyzed liquid-phase reaction of 2′-hydroxyacetophenone and benzaldehyde compared with non-functionalized mesoporous ZSM-5 (Meso ZSM-5) and functionalized microporous ZSM-5 (SO3H-ZSM-5). The higher loading of sulfonic acid functional groups led to higher acidity and consequently resulted in higher yield of products. The catalyst could be reused up to three cycles without significant loss in its catalytic activity.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 245, 1 May 2015, Pages 116–121
نویسندگان
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