کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5406806 | 1506049 | 2009 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Proton NMR studies of the NaAlH4 structure
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Advanced nuclear magnetic resonance (NMR) techniques were applied to study the local environments of hydrogen in NaAlH4. Through a combined application of the magic echo (ME) and the magic Hahn echo (MHE) sequences the hetero- and homonuclear contributions to the dipolar second moment (M2) were determined separately. The obtained values are compared with the second moments calculated by the van Vleck formulae, using structural data determined by neutron scattering on NaAlD4. This comparison indicates structural differences between NaAlH4 and NaAlD4. A model is suggested for the orientation of the [AlH4]â tetrahedra in NaAlH4, for which the calculated second moments are in good agreement with the experimentally observed values.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 200, Issue 2, October 2009, Pages 280-284
Journal: Journal of Magnetic Resonance - Volume 200, Issue 2, October 2009, Pages 280-284
نویسندگان
L.E. Valiente-Banuet, G. Majer, K. Müller,