کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5407808 | 1393232 | 2006 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Design, construction, and validation of a 1-mm triple-resonance high-temperature-superconducting probe for NMR
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Design, construction, and validation of a 1-mm triple-resonance high-temperature-superconducting probe for NMR Design, construction, and validation of a 1-mm triple-resonance high-temperature-superconducting probe for NMR](/preview/png/5407808.png)
چکیده انگلیسی
We report a 600-MHz 1-mm triple-resonance high-temperature-superconducting (HTS) probe for nuclear magnetic resonance spectroscopy. The probe has a real sample volume of about 7.5 μl, an active volume of 6.3 μl, and appears to have the highest mass sensitivity at any field strength. The probe is constructed with four sets of HTS coils that are tuned to 1H, 2H, 13C, and 15N, and there is a z-axis gradient. The coils are cooled with a conventional Bruker CryoPlatform to about 20 K, and the sample chamber can be regulated above or below room temperature over a moderate range using a Bruker variable temperature unit. The absolute S/N for 0.1% ethylbenzene is approximately 1/3 that of a conventional 5 mm probe with just 1/70 of the sample volume. We demonstrate the utility of this probe for small molecules and proteins with 2D spectra of just 1.7 μg of ibuprofen and 400 μM 15N-labeled ubiquitin.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Magnetic Resonance - Volume 179, Issue 2, April 2006, Pages 290-293
Journal: Journal of Magnetic Resonance - Volume 179, Issue 2, April 2006, Pages 290-293
نویسندگان
William W. Brey, Arthur S. Edison, Robert E. Nast, James R. Rocca, Saikat Saha, Richard S. Withers,