کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5421281 | 1507875 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
STM observation of the chemical reaction of atomic hydrogen on the N-adsorbed Cu(001) surface
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: STM observation of the chemical reaction of atomic hydrogen on the N-adsorbed Cu(001) surface STM observation of the chemical reaction of atomic hydrogen on the N-adsorbed Cu(001) surface](/preview/png/5421281.png)
چکیده انگلیسی
Chemical reaction of atomic hydrogen with the N-adsorbed Cu(001) surfaces was investigated at room temperature by scanning tunnel microscopy. At the low exposure of atomic hydrogen, it reacted with the N atoms and turned to be the NH species on the surface. The reaction rate is proportional to the amount of the unreacted N atoms. By increasing the exposure of atomic hydrogen from this condition, the amount of nitrogen species on the surface decreased. This is attributed to the formation of ammonia and its desorption from the surface. The NH species on the surface turn to NH3 through the surface NH2 species by atomic hydrogen. Coexistence of the clean Cu surface enhances the rate of ammonia formation owing to atomic hydrogen migrating on the clean surface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 655, January 2017, Pages 1-6
Journal: Surface Science - Volume 655, January 2017, Pages 1-6
نویسندگان
Takuma Hattori, Masamichi Yamada, Fumio Komori,