کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5424255 | 1507958 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mechanism of short-range interfacial repulsion between hydrated phosphatidylcholine bilayers: Comparison with phosphatidylethanolamine
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The grand canonical Monte Carlo technique is used to reveal the origin of the repulsive pressure operating between supported DLPC bilayers at short separations. By partitioning the interbilayer pressure into physically distinct components, it is shown that the short-range repulsion comes mainly from the direct electrostatic lipid-lipid interaction of the head groups in the opposing leaflets. By contrast, the electrostatic lipid-lipid interaction between DLPE bilayers is strongly attractive, and the short-range repulsion is associated with the hydration (water-lipid) interactions [A. Pertsin, D. Platonov, M. Grunze, Langmuir 23 (2007) 1388]. These findings explain why DLPC bilayers have a much larger interbilayer (fluid) separation at a given pressure, as compared to that for DLPE.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 603, Issues 10â12, 1 June 2009, Pages 1937-1944
Journal: Surface Science - Volume 603, Issues 10â12, 1 June 2009, Pages 1937-1944
نویسندگان
M. Grunze, I. Fedyanin, A. Pertsin,