کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5424514 | 1395827 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nano size effects in the high resolution electron energy loss spectra and excitation function of hydrogenated diamond films
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
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چکیده انگلیسی
The present work studies the high resolution electron energy loss spectra (HR-EELS) and excitation function of hydrogenated diamond films composed of diamond grains of varying size of â¼ 300, â¼ 20Â nm and â¼ 5Â nm. It is reported that HR-EELS modes associated with C-C lattice phonons are comparably more intense than modes associated with the C-H surface vibrational modes in the case of nano-crystalline compared to micro-crystalline diamond films. Excitation function measurements of the different modes show a pronounced maximum at â¼ 8Â eV for the nano-diamond films, whereas for micro-crystalline films similar modes showed maximum intensities at 13Â eV with a smaller contribution at 8Â eV. It is reported that the elastic electron reflectivity is substantially larger for the nano-diamond films, showing broad maxima at â¼ 8 and â¼ 13Â eV in both cases. It is suggested that these effects are associated with the larger probability for inelastic scattering of electrons by lattice phonons mediated by scattering with internal grain boundaries and defects in the case of nano-crystalline diamond films.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 602, Issue 18, 15 September 2008, Pages 3026-3032
Journal: Surface Science - Volume 602, Issue 18, 15 September 2008, Pages 3026-3032
نویسندگان
A. Hoffman, A. Lafosse, Sh. Michaelson, M. Bertin, R. Azria,