کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5424890 1395841 2008 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Reversed surface segregation in palladium-silver alloys due to hydrogen adsorption
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Reversed surface segregation in palladium-silver alloys due to hydrogen adsorption
چکیده انگلیسی
It is well known that silver segregates to the surface of pure and ideal Pd-Ag alloy surfaces. By first-principles band-structure calculations it is shown in this paper how this may be changed when hydrogen is adsorbed on a Pd-Ag(1 1 1) surface. Due to hydrogen binding more strongly to palladium than to silver, there is a clear energy gain from a reversal of the surface segregation. Hydrogen-induced segregation may provide a fundamental explanation for the hydrogen or reducing treatments that are required to activate hydrogen-selective membrane or catalyst performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 602, Issue 17, 1 September 2008, Pages 2840-2844
نویسندگان
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