کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5425707 | 1395863 | 2006 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Initial oxidation kinetics and energetics of Cu0.5Au0.5 (0 0 1) film investigated by in situ ultrahigh vacuum transmission electron microscopy
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The initial oxidation behavior of Cu0.5Au0.5 (0Â 0Â 1) thin film was investigated by in situ ultrahigh vacuum transmission electron microscopy to model nano-oxidation of alloys with one active component and one noble component. The formation of irregular-shaped octahedron Cu2O islands with cube-on-cube crystallographic orientation to the substrate film was observed at all temperature studied. The energetics of Cu2O nucleation for Cu and Cu0.5Au0.5 oxidation was compared. Cu0.5Au0.5 oxidation has lower nucleation activation energy due to the reduced mismatch strain between Cu2O and Cu0.5Au0.5 films. On the other hand, the reaction kinetics for Cu0.5Au0.5 alloy oxidation is slower due to the higher diffusion activation energy of Cu.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 600, Issue 11, 1 June 2006, Pages 2372-2378
Journal: Surface Science - Volume 600, Issue 11, 1 June 2006, Pages 2372-2378
نویسندگان
Liang Wang, Guang-Wen Zhou, Jeffrey A. Eastman, Judith C. Yang,