کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5426089 | 1395874 | 2007 | 6 صفحه PDF | دانلود رایگان |
Using temperature-variable scanning tunneling microscopy, we studied the coalescence of vacancy islands on Cu(0Â 0Â 1) in ultra-high vacuum. From the temperature dependence of the relaxation of merged vacancy islands to the equilibrium shape we obtain an activation energy of the island coalescence process of 0.76Â eV. From that value we deduce an activation energy for the atomic hopping coefficient of EÎh=0.89Â eV. Comparing our result with previous STM data on step fluctuations with dominant diffusion along straight step segments (EÎh=0.68Â eV; [M. Giesen, S. Dieluweit, J. Mol. Catal. A: Chem. 216 (2004) 263]) and step fluctuations with kink crossing (EÎh=0.9Â eV; [M. Giesen-Seibert, F. Schmitz, R. Jentjens, H. Ibach, Surf. Sci. 329 (1995) 47]), we conclude that there is a large extra barrier for diffusion of atoms across kinks on Cu(0Â 0Â 1) of the order of 0.23Â eV. This is the first direct experimental evidence for the existence of a large kink Ehrlich-Schwoebel barrier on Cu(0Â 0Â 1).
Journal: Surface Science - Volume 601, Issue 5, 1 March 2007, Pages 1403-1408