کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5435636 | 1509353 | 2017 | 5 صفحه PDF | دانلود رایگان |
- The SG-CNT Buckypapers and the SG-CNT/Hydrazine/Polymer show good thermoelectric properties.
- The n-type SG-CNT Buckypapers are easily oxidized by oxygen in air.
- The CNT/Hydrazine/PVC films are stable in air and kept negative Seebeck coefficient after 28 days.
In order to fabricate effective Î -form thermoelectric devices both positive-type (p-type) and negative-type (n-type) semiconductors are expected to be used for the fabrication. There are a few reports on n-type organic thermoelectric materials and they are usually unstable in air. Here, we report the considerable stabilization of n-type carbon nanotubes/hydrazine hybrid films by mixing a common polymer, poly(vinyl chloride) (PVC) and poly(vinylidene difluoride) (PVDF). The n-type carbon nanotubes were synthesized by dispersion of super growth carbon nanotubes (SG-CNTs) into hydrazine hydrate in NMP (N-methyl-2-pyrrolidone). The SG-CNT/Hydrazine/PVC hybrid films were fabricated by a simple method to drop-cast the mixtures on a glass substrate. To evaluate the air durability of SG-CNT/Hydrazine/PVC hybrid film, the samples were kept in air and the temporal change of the thermoelectric properties in air was measured. After 150 min Seebeck coefficients of n-type SG-CNT without polymer changed from â5.0 μV Kâ1 to 7.0 μV Kâ1. On the other hand, the SG-CNT/Hydrazine/PVC hybrid films were rather stable in air and kept negative Seebeck coefficient even after 28 days.
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Journal: Synthetic Metals - Volume 225, March 2017, Pages 81-85