کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5437878 | 1398178 | 2017 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
NiCo2O4 nanosheets and nanocones as additive-free anodes for high-performance Li-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
Development of novel electrode materials with high energy and power densities for lithium-ion batteries (LIBs) is the key to meet the demands of electric vehicles. Transition metal oxides that can react with large amounts of Li+ for electrochemical energy storage are considered promising anode materials for LIBs. In this work, NiCo2O4 nanosheets and nanocones on Ni foam have been synthesized via general hydrothermal growth and low-temperature annealing treatment. They exhibit high rate capacities and good cyclic performance as LIB anodes owing to their architecture design, which reduces ion and electron transport distance, expands the electrode-electrolyte contact, increases the structural stability, and buffers volume change during cycles. Notably, NiCo2O4 nanosheets deliver an initial capacity of 2239 mAh gâ1 and a rate capacity of 964 mAh gâ1 at current densities of 100 and 5000 mA gâ1, respectively. The corresponding values of nanocones are 1912 and 714 mAh gâ1. Hence, the as-synthesized NiCo2O4 nanosheets and nanocones, which are carbon-free and binder-free with higher energy densities and stronger connections between active materials and current collectors for better stability, are promising for use in advanced anodes for high-performance LIBs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Issue 16, November 2017, Pages 13710-13716
Journal: Ceramics International - Volume 43, Issue 16, November 2017, Pages 13710-13716
نویسندگان
Qing-Qing Ren, Zhen-Bo Wang, Ke Ke, Si-Wen Zhang, Bo-Si Yin,