کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5437952 1398179 2017 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phase structural transition and microwave dielectric properties in isovalently substituted La1−xLnxTiNbO6 (Ln=Ce, Sm) ceramics
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Phase structural transition and microwave dielectric properties in isovalently substituted La1−xLnxTiNbO6 (Ln=Ce, Sm) ceramics
چکیده انگلیسی
Aeschynite-type La1−xLnxTiNbO6 (Ln=Ce, Sm, x=0-1) ceramics were prepared via a conventional solid state method. Analysis of X-ray diffraction, Raman, infrared reflectivity spectra and the microstructures revealed a series of composition-induced phase evolution in sequence: monoclinic→coexistence of monoclinic and orthorhombic→orthorhombic structure, i.e. M→M+O→O. The critical compositions of distinguishing the dominant M or O phase were x=0.15 in La1−xCexTiNbO6 and x=0.10 in La1−xSmxTiNbO6 ceramics, exactly corresponding to the average ionic radius of rare earth ions (IR) ~1.027 Å. The crystal structure and microwave dielectric properties of RETiNbO6 (RE=rare earth) ceramics strongly depended on IR. Near-zero τf was achieved in the Ce-sample with x=0.153 (εr=28.9, Q×f=17,275 GHz@6.54 GHz) as well as in the Sm-sample with x=0.098 (εr=28.2, Q×f=19,186 GHz@6.78 GHz). Eventually, RETiNbO6 would form O euxenite (-τf), O aeschynite (+τf), and M aeschynite (-τf), as IR<0.945 Å, 0.945 Å
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Issue 9, 15 June 2017, Pages 7065-7072
نویسندگان
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