کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5438344 | 1398183 | 2017 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of carbon coated Bi2O3 nanocomposite anode for sodium-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Bi2O3 is a promising sodium storage material due to its high gravimetric specific capacity. However, Bi2O3 possesses lower electrochemical performance due to its poor electrical conductivity and structural integrity during Na+ insertion/extraction process. Here, we prepared a carbon coated Bi2O3 nanocomposite by a redox reaction and a carbon coating process. In this nanocomposite, the carbon layer can avoid the direct contact between Bi2O3 and electrolyte, which inhibits the repeated formation and decomposition of solid electrolyte interface film. Additionally, the carbon layer can enhance the electrical conductivity of Bi2O3 and suppress its aggregation due to its volume change during charge and discharge process. In addition, nano-sized Bi2O3 can reduce the transport distance of Na+ and electron. The nanocomposite shows excellent cycling performance and rate capability as anode for sodium-ion batteries. A high capacity of 421 mAh gâ1 can be maintained after 100 cycles at 1500Â mAÂ gâ1 and 392 mAh gâ1 can be shown at 3200 mAh gâ1.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Issue 12, 15 August 2017, Pages 8819-8823
Journal: Ceramics International - Volume 43, Issue 12, 15 August 2017, Pages 8819-8823
نویسندگان
Wei Fang, Lishuang Fan, Yu Zhang, Qi Zhang, Yanyou Yin, Naiqing Zhang, Kening Sun,