کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5438730 | 1398187 | 2016 | 26 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Dielectric properties and relaxation behaviors of Ba doped Sr0.97Sm0.02TiO3 ceramics in different sintering atmospheres
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The BaxSr0.97âxSm0.02TiO3 (x=0-0.4) ceramics in different sintering atmosphere were prepared by conventional solid-state reaction methods. The effect of different atmosphere on the dielectric properties of BaxSr0.97âxSm0.02TiO3 ceramics was investigated. The giant permittivity was obtained for BaxSr0.97âxSm0.02TiO3 ceramics sintered in nitrogen especially for x=0.2, which exhibited a weak temperature- and frequency- dependent giant permittivity (>104) as well as a low dielectric loss (mostly <0.05) over a broad temperature range from 20 to 300 °C. Based on the relaxation behaviors, XPS Spectrum and complex- impedance analysis of ceramics in different sintering atmosphere, the giant permittivity and low dielectric loss were due to the existence of the giant defect dipoles [Ti4+·e -Vo..- e·Ti4+] generated by the fully ionized oxygen vacancies and Ti3+ ions, while the defect dipoles (VSr,,âVo..) and interfacial polarization caused the dielectric relaxation of the ceramics sintered in air or O2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 42, Issue 15, 15 November 2016, Pages 16782-16788
Journal: Ceramics International - Volume 42, Issue 15, 15 November 2016, Pages 16782-16788
نویسندگان
Guangyao Li, Hanxing Liu, Hua Hao, Jiajia Liu, Zhuo Chen, Xindi Huang, Minghe Cao, Zhonghua Yao,