کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5438835 | 1398188 | 2017 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation and characterization of Li0.30Cr0.10Ni0.60O/polyvinylidene fluoride composites with high dielectric constants
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Lithium chromium nickel oxide (Li0.30Cr0.10Ni0.60O, LCNO) materials were prepared by sol-gel process and calcined at the temperature of 1000 °C for 3 h. Mechanical mixing process and hot pressing fabricated the composites between LCNO and polyvinylidene fluoride (PVDF). Effects of the amount of LCNO filler on the structure and dielectric properties of LCNO/PVDF composites were investigated. The LCNO/PVDF composites were characterized by thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Furthermore, the dielectric properties of the LCNO/PVDF composites were also investigated. From TGA results, the decomposition step of LCNO/PVDF composites depends on the LCNO content and weight loss decrease with increasing LCNO contents due to the presence of LCNO in PVDF. All LCNO/PVDF composites exhibited two-phase structures of cubic rock-salt NiO structure and α-, γ- phases of PVDF. It is revealed that dielectric constant of the polymer composite increases with increasing LCNO content. This might be due to the formation of micro-capacitor network. The LCNO/PVDF composite with amount of 30 wt% showed the best properties with a high dielectric constant of 59.27 and low loss tangent of 0.31 at the frequency of 1 kHz and at room temperature. The composite gave a high dielectric constant, which was 2.82 times higher than that of pure PVDF. Therefore, the ï¬exible high dielectric constant and low loss tangent of the composite were weakly frequency dependent, which might be suitable for capacitor applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Supplement 1, August 2017, Pages S274-S279
Journal: Ceramics International - Volume 43, Supplement 1, August 2017, Pages S274-S279
نویسندگان
Bualan Khumpaitool, Songkot Utara,