کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5439002 | 1398190 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
AC, DC conduction and dielectric behaviour of solid and liquid phase sintered Al2O3-15Â mol% V2O5 pellets
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Microstructural and dielectric characterization of porous Al2O3-V2O5 pellets sintered under both solid (600 °C) and liquid phase (850 °C) conditions are reported. The low temperature solid state sintering (SSS) leaves a very porous network of dense alumina particles surrounded by smaller facetted vanadia, whereas under liquid phase sintering (LPS), the V2O5 melts and recrystallizes over the relatively inert Al2O3, leading to a connected network structure. The ac conductivity and dielectric parameters of the pellets investigated from room temperature (RT) to 400 °C exhibited both universal dielectric (diffusive) behaviour at low frequencies and nearly constant loss (sub-diffusive) regimes at low temperatures. Activation energies calculated for dc/ac conduction at different frequencies suggests a composite conduction mechanism controlled by the Vanadia phase: at low frequencies, the calculated energies (Eaâ0.5 eV) compare with ionic diffusion of vanadium in V2O5, while at high frequencies and low temperatures an additional (Eaâ¤0.16 eV) polaronic hopping mechanism is seen. This cross-over frequency is significant for the LPS specimen indicating that the vanadia connected network assists conduction by providing a continuous (but disordered) diffusion route. Impedance and modulus spectral analysis show the presence of distributed time constants arising from electrodes, pore/matrix and phase interfaces and GBs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Ceramics International - Volume 43, Issue 3, 15 February 2017, Pages 3202-3211
Journal: Ceramics International - Volume 43, Issue 3, 15 February 2017, Pages 3202-3211
نویسندگان
S. Seethalakshmi, B. Subramanian, Avi Bendavid, A.K. Nanda Kumar,