کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5440237 | 1510140 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Structure, stability and permeation properties of NaA zeolite membranes for H2O/H2 and CH3OH/H2 separations
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
NaA zeolite membranes were synthesised in the secondary growth hydrothermal method based on the seeding of the inner surface of a ceramic α-alumina tube. The impacts of crystallisation time and zeolite precursor concentration (in H2O) were investigated. The structure and stability of the prepared NaA zeolite membranes were also investigated with operating temperatures, times and pressures. The results indicate that the optimal synthesis gel molar composition was 3Na2O: 2SiO2: Al2O3: 200H2O. This led to cubic-shaped NaA zeolite which showed good stability. The optimal NaA zeolite membrane had H2O and CH3OH fluxes of 2.77 and 0.19 kg/m2h, with H2O/H2 and CH3OH/H2 separation factors of â and 0.09 at a temperature of 30 °C. The NaA zeolite membrane had high thermal stability, but poor separation performance at high temperature (240 °C). The results suggested that the H2 permeation flux is significantly influenced by preferential adsorption of vapour in the NaA zeolite membrane.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of the European Ceramic Society - Volume 38, Issue 1, January 2018, Pages 211-219
Journal: Journal of the European Ceramic Society - Volume 38, Issue 1, January 2018, Pages 211-219
نویسندگان
Sang Moon Lee, Nong Xu, John R. Grace, Anwu Li, C. Jim Lim, Sung Su Kim, Farzam Fotovat, Achim Schaadt, Robin J. White,