کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5442103 | 1398281 | 2017 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Mo-N-co-doped mesoporous TiO2 microspheres with enhanced visible light photocatalytic activity Mo-N-co-doped mesoporous TiO2 microspheres with enhanced visible light photocatalytic activity](/preview/png/5442103.png)
- The Mo-N-co-doped mesoporous TiO2 microspheres were synthesized via a solvothermal method and further nitriding treatment.
- The properties of TiO2 microspheres can be tuned by Mo-N-co-doping.
- Photocatalytic rate is much higher than Pure TiO2 catalyst powder and Mo doped TiO2 microspheres.
- The higher activity is attributed to the large BET surface area, narrow band gap and intense light absorbance in visible region.
Mo-N-co-doped mesoporous TiO2 microspheres were synthesized via a solvothermal method, followed by nitriding treatment under ammonia gas flow. The efficiency of the samples was investigated by monitoring the degradation of Rhodamine-B under visible light irradiation. The experimental results revealed that Mo-N-co-doped mesoporous TiO2 microspheres showed better performances than Mo-TiO2 microspheres. It was observed that; 0.1% molar quantity of Mo doped on TiO2 at 500 °C for 2 h under nitriding conditions gave highest photocatalytic activities. The nitridation under ammonia gas of Mo-TiO2 samples created oxygen vacant sites and led to incorporation of substitutional and interstitial Nitrogen. The enhanced visible light photocatalytic activities of Mo-N-co-doped TiO2 photocatalyst was attributed to the large surface areas, narrow band gap and intense light absorbance in visible region. This study may create a promising and eco-friendly method towards synthesis of metal and non-metals co-doped on semiconductor materials to improve their photocatalytic activities and applications.
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Journal: Materials Research Bulletin - Volume 96, Part 1, December 2017, Pages 10-17