کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5447236 | 1511496 | 2017 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The study of the thermal behavior of solid mixtures of metakaolin and sodium hydroxide by isoconversional model-free analyzes
ترجمه فارسی عنوان
مطالعه رفتار حرارتی مخلوط جامد متاکائولین و هیدروکسید سدیم با استفاده از تجزیه و تحلیل آزاد
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
چکیده انگلیسی
Interactions in solid mixtures of 6Al2Si2O7: 12NaOH and 6Al2Si2O7: 12NaOH: 2Al2O3 under thermal treatment were studied. Ultrasonic pre-treatment of suspensions with a frequency of 22 kHz was applied. X-ray phase analysis, scanning electron microscopy, and synchronous thermal analysis were used in this research. It was shown that after evaporation of the suspensions, the hydrated LTA zeolite and sodium hydroaluminate are synthesized. During thermal treatment up to 500 °C, the adsorption water is removed first and then the dehydration of the zeolite and hydroaluminate occurs. Calcination at temperatures above 500° C leads to the synthesis of Na6Al4Si4O17 and Na8Al4Si4O18 by the interaction of metakaolin and zeolite with sodium hydroxide. At temperatures above 700 °C, the formation of mullite and nepheline occurs in the temperature range of 500-800 °C. The kinetic parameters have been calculated using Friedman analysis (differential method), Kissinger-Akahira-Sunose and Ozawa-Flynn-Wall analyzes (integral methods). It was shown that all analyzes give similar dependences of the apparent activation energy vs the conversion extent and the values of E are in the range of 70-350 kJ molâ1. It was established that ultrasonic pre-treatment allows to reduce the values of the apparent activation energy. It was discovered that the Al2O3 excess over the stoichiometry of the LTA zeolite synthesis is an inhibitor of the mullite and nepheline formation reactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 110, November 2017, Pages 297-306
Journal: Journal of Physics and Chemistry of Solids - Volume 110, November 2017, Pages 297-306
نویسندگان
Natalya E. Gordina, Valery Yu Prokof'ev, Nikolay N. Smirnov, Alexandra P. Khramtsova,