کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5457025 1515119 2017 13 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Probing the oxidative etching induced dissolution of palladium nanocrystals in solution by liquid cell transmission electron microscopy
ترجمه فارسی عنوان
آزمایش اکتیو اکسیداتیو باعث انحلال نانوبلورهای پالادیوم در محلول با میکروسکوپ الکترونی انتقال سلول های مایع
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد دانش مواد (عمومی)
چکیده انگلیسی
A microscopic study of dissolution process of nanocrystals, an opposite while functioning cooperatively with growth in many cases, is an essential issue in variety aspects of research on nanocrystals. In this work, an in situ study of the dynamic dissolution process of palladium nanocrystals by liquid cell transmission electron microscope (TEM) is presented. The effective critical size (Rcritical) for monodispersed nanocrystals is determined to be about 5 nm in the experimental condition of this article. When the size of nanocrystal is above Rcritical, the dissolution rate (dr/dt) is nearly a constant. For the nanocrystal sizing below Rcritical, the dissolution rate (dr/dt) increases with the decrease of the nanocrystal radius r, indicating that high equilibrium solubility must be taken into account in the dissolution rate of small nanocrystals in solution. It is found that the aggregation kinetics and confinement effect between adjacent nanocrystals have effects on the dissolution rate during the reaction, and it has been analyzed in details and discussed in terms of the underlying physics involved. Lastly, the effects of electron beam-water interaction and the iron (III) agents on the oxidative etching are also compared.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Micron - Volume 97, June 2017, Pages 22-28
نویسندگان
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